作者：朱婧晶主编
页数：122
出版社：西安电子科技大学出版社
出版日期：2018
ISBN：9787560648705
电子书格式：pdf/epub/txt
内容简介
本书包含热力学和统计物理学两部分内容。全书共七章，分别是热力学的基本规律、均匀物质的热力学性质、相变、化学反应平衡和热力学第三定律、近独立粒子的最概然分布、玻尔兹曼统计、系综理论。
本书可作为大学物理专业的教材和相关专业参考书，也可以作为介绍现代热力学和统计物理学的科普书，还可作为一本内容丰富的科技英语阅读参考书。
本书特色
本书包含热力学和统计物理学两部分内容。全书共七章，分别是热力学的基本规律、均匀物质的热力学性质、相变、化学反应平衡和热力学第三定律、近独立粒子的最概然分布、玻尔兹曼统计、系综理论。本书可作为大学物理专业的教材和相关专业参考书，也可以作为介绍现代热力学和统计物理学的科普书，还可作为一本内容丰富的科技英语阅读参考书。
目录
§ 1.1 Equilibrium state and description of thermodynamic system 1
§ 1.2 Thermal equilibrium and temperature－the zeroth law of thermodynamics 4
§ 1.3 Equation of state 6
§ 1.4 Work 10
§ 1.5 The first law of thermodynamics 11
§ 1.6 Heat capacity and enthalpy 14
§ 1.7 Internal energy of an ideal gas 15
§ 1.8 Adiabatic process of an ideal gas 18
§ 1.9 Carnot cycle of an ideal gas 19
§ 1.10 The second law of thermodynamics 22
§ 1.11 Carnot’s theorem and Clausius inequality 24
§ 1.12 Entropy and the central equation of thermodynamics 26
§ 1.13 The free energy and Gibbs function 29
Exercises 30
Chapter 2 Thermodynamic Properties of the Uniform System 33
§ 2.1 Maxwell’s relations 33
§ 2.2 The application of Maxwell’s relations 36
§ 2.3 The throttling process and adiabatic expansion of gas 38
§ 2.4 Determination of the basic thermodynamic functions 40
§ 2.5 Specific functions 42
Exercises 43
Chapter 3 Phase Transitions 45
§ 3.1 The criterion of thermodynamic dynamic equilibrium 45
§ 3.2 Thermodynamic basic equations of open systems 48
§ 3.3 The complex phase equilibrium condition of a single component system 50
§ 3.4 The Clausius睠lapeyron equation 53
§ 3.5 Classification of phase transitions 56
Exercises 59
Chapter 4 The Equilibrium of Chemical Reactions and the third Law of Thermodynamics 61
§ 4.1 Thermodynamic functions and equations of a multicomponent system 61
§ 4.2 The complex phase equilibrium condition of a multicomponent system 65
§ 4.3 The Gibbs phase rule 66
§ 4.4 Equilibrium of chemical reaction 67
§ 4.5 The law of mass action 70
§ 4.6 The third law of thermodynamics 73
Exercises 77
Chapter 5 The Most Probable Distribution of Nearly Independent Particles 80
§ 5.1 The classical description of the motion state of particle 80
§ 5.2 The quantum description of the motion state of particle 84
§ 5.3 The description of microstate of system 89
§ 5.4 Distribution and microscopic states 92
§ 5.5 Maxwell睟oltzmann distribution, Bose睧instein distribution and Fermi睤irac distribution 93
Exercises 96
Chapter 6 Boltzmann Statistics 97
§ 6.1 The statistical definitions of thermodynamic quantities 97
§ 6.2 The Maxwell velocity distribution 100
§ 6.3 The equipartition theorem of energy 102
§ 6.4 The internal energy, heat capacity and entropy of an ideal gas 105
Exercises 107
Chapter 7 Ensemble Theory 109
§ 7.1 Phase space and Liouville’s theorem 109
§ 7.2 The microcanonical ensemble 112
§ 7.3 The canonical ensemble 116
§ 7.4 The grand canonical ensemble 118
Exercises 120
Bibliography 122
