
作者:Zbigniew H. Stachurs
页数:359
出版社:高等教育出版社
出版日期:2023
ISBN:9787040601282
电子书格式:pdf/epub/txt
内容简介
金属玻璃和非晶合金作为新一类材料,由于其独特的结构和性能特点,已在航空航天、汽车和电子等领域得到广泛应用。本书根据材料的发展历史和金属的凝固特点,通过丰富的图表和生动的文字,详细介绍了非晶金属和金属玻璃的基础知识、制备方法、结构特点、表征方法和应用等,并通过征引多篇重要的科学文献,凸显出非晶金属和金属玻璃所具有的独特的弹性和滞弹性、塑性变形和相关机理、断裂性能和相关机制,以及磁性能等。本书适合材料科学和凝聚态物理领域的科研人员和工程技术人员阅读,也可作为高等院校材料科学专业师生的教学参考。
作者简介
Zbigniew H.Stachurski,澳大利亚国立大学教授。1991年当选澳大利亚皇家化学学会会员,1993年获皇家化学学会“聚合物材料突出贡献奖”。2002年任澳大利亚国立大学材料中心主任。Stachurski教授长期致力于非晶合金的研究,在该领域已经发表100余篇学术论文,出版学术专著3部。
王刚,上海大学教授,德国洪堡学者。2019年获得国家自然科学基金委“杰出青年科学基金”。2012年获得国家自然科学基金委“优秀青年科学基金”。主要研究方向为:高能同步辐射研究非晶合金的原位变形行为和低温(液氮温区)结构转变;非晶合金弹一塑性变形行为;玻璃材料断裂损伤行为;新型高熵合金开发。发表SCI论文200余篇,被引总数为7500余次,H指数为40。
谭晓华,上海大学材料科学与工程学院研究员,博士生导师。主要从事磁性非晶、高熵合金和钕铁硼磁性材料研究工作。发表SCI论文100余篇,获国家授权专利8项。
目录
CHAPTER 1 Introduction
References
CHAPTER 2 Making of metallic glasses and applications
2.1 Applications of metallic glasses
Aerospace and beyond
Protective shield
Application as compliant mechanisms
Application as gears
Application as mirrors
Application to corrosion resistance
Application to solar wind collection
Application as magnetic sensors
Application as super-conducting sensors
Biological applications of metallic glasses
Recent developments of metallic glasses as biomaterials
Mg60Zn35Cas alloy
Ti40Cu36Pd14Zr10 alloy
Non-degradable metallic glasses (Ti-, Zr-, Fe-, Pt-based MGs)
Zr-based metallic glasses
Fe-based metallic glasses
Pt-based metallic glasses
Mg-, Zn-, Ca-, Sr-based metallic glasses
Metallic glass transformers
Sporting equipment and personal items
Optical, magnetic, and electrical
Amorphous silicon solar cells
Jewellery
Metallic plasticine
Rewritable DVDs
Manufacturing process
How the material functions in a system
References
2.2 Making metallic glasses
Casting into a mold
Spinning wheel method
High-pressure torsion
Ti-Ni alloy
Fe78B8.5SigP4.5 alloy
ZrTiNiCu alloy
Ball milling
Cold rolling
References
CHAPTER 3 Solidification
3.1 Solidification by crystallization
Liquid → solid transformation by crystallization
Nucleation
Nucleation phenomenon and physical process
Nucleation kinetics
Embryos, nuclei, and critical size
Temperature dependence of nucleation
Structural dependence of nucleation
Crystal growth
Viscosity
Kinetics of crystallization
Assumptions for isothermal crystallization
Homogeneous nucleation and spherical growth
Instantaneous heterogeneous nucleation and spherical growth
Random nucleation and surface growth
Random nucleation and diffusion controlled spherical growth
Microstructure of solidified metals
Stereology of micro-structures
Analysis of the KJMA equation
Temperature dependence of the crystallization rate
References
3.2 Solidification of glass
The process
Use of the terms “amorphous” and “glass”
Variety of glasses
Three characteristics common to all glasses
Diffuse halo X-ray scattering pattern
Step at Tg on DSC curve
Gradient change at Tg in dilatometry
Relationship between cooling rate and vitrification
TTT diagram for aluminium
Continuous cooling transformation (CCT) diagrams
Brief history of metallic glasses
Glass-forming ability
Reduced glass transition temperature
Fragility
The cage effect
References
CHAPTER 4 Characterization of metallic glasses
CHAPTER 5 Models of structure
CHAPTER 6 Magnetic properties of amorphous metallic alloys
CHAPTER 7 Elasticity of metallic gasses
CHAPTER 8 Introduction to anelastic deformation
CHAPTER 9 Plastic deformation and yield strength of metals
CHAPTER 10 Fracture mechanics of metallic glasses
APPENDIX A Thermodynamics of a system
INDEX
References
CHAPTER 2 Making of metallic glasses and applications
2.1 Applications of metallic glasses
Aerospace and beyond
Protective shield
Application as compliant mechanisms
Application as gears
Application as mirrors
Application to corrosion resistance
Application to solar wind collection
Application as magnetic sensors
Application as super-conducting sensors
Biological applications of metallic glasses
Recent developments of metallic glasses as biomaterials
Mg60Zn35Cas alloy
Ti40Cu36Pd14Zr10 alloy
Non-degradable metallic glasses (Ti-, Zr-, Fe-, Pt-based MGs)
Zr-based metallic glasses
Fe-based metallic glasses
Pt-based metallic glasses
Mg-, Zn-, Ca-, Sr-based metallic glasses
Metallic glass transformers
Sporting equipment and personal items
Optical, magnetic, and electrical
Amorphous silicon solar cells
Jewellery
Metallic plasticine
Rewritable DVDs
Manufacturing process
How the material functions in a system
References
2.2 Making metallic glasses
Casting into a mold
Spinning wheel method
High-pressure torsion
Ti-Ni alloy
Fe78B8.5SigP4.5 alloy
ZrTiNiCu alloy
Ball milling
Cold rolling
References
CHAPTER 3 Solidification
3.1 Solidification by crystallization
Liquid → solid transformation by crystallization
Nucleation
Nucleation phenomenon and physical process
Nucleation kinetics
Embryos, nuclei, and critical size
Temperature dependence of nucleation
Structural dependence of nucleation
Crystal growth
Viscosity
Kinetics of crystallization
Assumptions for isothermal crystallization
Homogeneous nucleation and spherical growth
Instantaneous heterogeneous nucleation and spherical growth
Random nucleation and surface growth
Random nucleation and diffusion controlled spherical growth
Microstructure of solidified metals
Stereology of micro-structures
Analysis of the KJMA equation
Temperature dependence of the crystallization rate
References
3.2 Solidification of glass
The process
Use of the terms “amorphous” and “glass”
Variety of glasses
Three characteristics common to all glasses
Diffuse halo X-ray scattering pattern
Step at Tg on DSC curve
Gradient change at Tg in dilatometry
Relationship between cooling rate and vitrification
TTT diagram for aluminium
Continuous cooling transformation (CCT) diagrams
Brief history of metallic glasses
Glass-forming ability
Reduced glass transition temperature
Fragility
The cage effect
References
CHAPTER 4 Characterization of metallic glasses
CHAPTER 5 Models of structure
CHAPTER 6 Magnetic properties of amorphous metallic alloys
CHAPTER 7 Elasticity of metallic gasses
CHAPTER 8 Introduction to anelastic deformation
CHAPTER 9 Plastic deformation and yield strength of metals
CHAPTER 10 Fracture mechanics of metallic glasses
APPENDIX A Thermodynamics of a system
INDEX














